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Abstract We present a versatile platform for fabricating two‐photon excitable carbon dot‐based nanocomposite thin films by harnessing the structural versatility of polymer brushes in combination with electron‐beam lithography (EBL). This approach enables the precise spatial organization of carbon dots (CDs) at the nanoscale, facilitating dynamic modulation of their photoluminescent properties in response to environmental stimuli. Three model systems were examined, incorporating pH‐ and thermally responsive polymers, functionalized through covalent and dynamic covalent bonding strategies. By leveraging the spatial control afforded by nanostructured polymer brushes, we achieved precise tuning of optical properties while mitigating aggregation‐induced quenching, a longstanding challenge in solid‐state CD applications. In addition to the advances in controlling optical properties, this work highlights the potential of polymer brush systems to function as optically active, reprogrammable surfaces. The resulting nanoscale‐engineered materials exhibit highly responsive, reconfigurable photonic behavior, offering a scalable pathway for integrating advanced optical interfaces into microchip technologies, biosensing platforms, and multiplexed diagnostic systems. The fusion of polymer brushes, carbon dots, and advanced lithographic techniques marks a substantial advancement in the development of functional materials with nanoscale precision and stimuli‐responsive properties. 

Abstract An acoustic liquefaction approach to enhance the flow of yield stress fluids during Digital Light Processing (DLP)‐based 3D printing is reported. This enhanced flow enables processing of ultrahigh‐viscosity resins (μ_app > 3700 Pa s at shear rates  = 0.01 s^–1) based on silica particles in a silicone photopolymer. Numerical simulations of the acousto–mechanical coupling in the DLP resin feed system at different agitation frequencies predict local resin flow velocities exceeding 100 mm s^–1at acoustic transduction frequencies of 110 s^–1. Under these conditions, highly loaded particle suspensions (weight fractions, ϕ = 0.23) can be printed successfully in complex geometries. Such mechanically reinforced composites possess a tensile toughness 2000% greater than the neat photopolymer. Beyond an increase in processible viscosities, acoustophoretic liquefaction DLP (AL‐DLP) creates a transient reduction in apparent viscosity that promotes resin recirculation and decreases viscous adhesion. As a result, acoustophoretic liquefaction Digital Light Processing (AL‐DLP) improves the printed feature resolution by more than 25%, increases printable object sizes by over 50 times, and can build parts >3 × faster when compared to conventional methodologies.